VG Scientific XPS Handbook E. Adem, VG Scientific, 1991 (1st edition) On-Screen PDF Handbook of Monochromatic XPS Spectra - Vol. 1 - The Elements and Native Oxides B. V. Crist, XPS International, Inc., 1999 On-Screen PDF Handbook of Monochromatic XPS Spectra - Vol. 2 - Commercially Pure Binary Oxides B. V. Crist, XPS International, Inc., 2005 X-ray Induced Auger Electrons General methods in assisting peak identification (1) Check peak positions and relative peak intensities of 2 or more peaks (photoemission lines and Auger lines) of an element (2) Check spin orbital splitting and area ratios for p, d, f peaks Handbook of X-Ray Photoelectron Spectroscopy J. Moulder, W. Stickle, +1 author K. D. Bomben Published 1992 Physics X-ray photoelectron spectroscopy (XPS) is a dedicated surface The surface of steel disc was examined by means of XPS technique, and its chemical Moulder J.F., Stickle W.F., Sobol P.E., Bomben K.D.: Handbook of X-ray. XPS imaging, which reveals the distribution of chemistries across a surface; angleresolved XPS, which can distinguish electrons from different depths in the surface of a sample; and charge compensation, which allows for the analysis of insulators. Some of these specialist implementations are discussed in forthcoming chapters. XPS Summary • Elemental sensitivity Range Li -U Excellent specificity Detection limits 0.1 -1 atomic % • Spatial resolution Few m for commercial systems • Analysis depth Depends on material and photoelectron energy Can sputter depth profile for larger depths From: U. Dayton J. Grant XPS short course • Quantitative X-Ray Photoelectron Spectroscopy. XPS is a surface chemical analysis technique that can be used to analyze the surface chemistry of a material in its "as received" state, or after some treatment, for example, fracturing, cutting, or scraping in air or UHV exposure, ion beam etching to clean off some of the surface contamination, exposure to heat to study the changes due to heating This book introduces readers interested in the field of X-ray Photoelectron Spectroscopy (XPS) to the practical concepts in this field. The book first introduces the reader to the language and concepts used in this field and then demonstrates how these concepts are applied. California Institute of Technology X-ray Photoelectron Spectroscopy (XPS), also known as Electron Spectroscopy for Chemical Analysis (ESCA) is a widely used technique to investigate the chemical composition of surfaces. X-ray Photoelectron spectroscopy, based on the photoelectric effect,1,2was developed in the mid-1960's by Kai X-ray Photoelectron Spectroscopy (XPS) 7. Photoemission Spectroscopy (XPS) 7.1 Principles 7.2 Interpretation 7.2.1 Notations 7.2.2 Electron workfunction 7.2.3 Chemical shifts 7.3 Instrumentation 7.4 XPS vs UV photoelectron spectroscopy (UPS) 7.5 Auger Electron Spectroscopy (AES) 7.6 Quantitative Analysis Appendix I: Workfunction X-ray photoelectron spectroscopy ( XPS) is a surface-sensitive quantitative spectroscopic technique based on the photoelectric effect that can identify the elements that exist within a material (elemental composition) or are covering its surface, as well as their chemical state, and the overall electronic structure and density of the electronic Abstract. X-ray photoelectron spectroscopy (XPS) is generally regarded as an important and key technique for the surface characterization and analysis of biomedical polymers. (1) This technique, also called ESCA (Electron
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